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9398 REACTIONS WHERE MORE THAN ONE REACTION CONTRIBUTES Observed rate 14 k2nd12PtðdienÞClþ12pyridine obs 321 ð8:10Þ 14 k1st 12PtðdienÞClþ obs ð8:11Þ where k2nd is a second order rate constant, k1st is a pseudo-first order rate constant obs obs and k1st 14k2nd12pyridine obs obs If the mechanism is correct, then k1st 12PtðdienÞClþ 14 k112PtðdienÞClþ12pyridine þ k212PtðdienÞClþ obs graph will go through the origin, and k2 will be zero.
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Et al. Ferguson, D. Significant changes in signal intensity between the two states were demonstrated in the thalamus, and basal ganglia, and these changes correlated inversely with tic severity.
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